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51.
Five vertical profiles of silver (Ag) in the subarctic northeast Pacific are presented. Dissolved (< 0.2 μm) Ag concentrations within the surface mixed layer range from 6–25 pM, with the highest observed values at the most coastal site. Elevated Ag concentrations at this station are most likely attributable to the estuarine circulation in the Juan de Fuca Strait. One open-ocean station (P20) exhibited a strong surface Ag maximum. The station was located at the edge of a Haida eddy which raises the possibility that such eddies transport Ag seaward from the coastal zone. Ag concentrations in the deep waters ranged from 60–80 pM. These measurements are consistent with other recent Ag data collected in the Pacific. Ag profiles throughout the Pacific Ocean yield a strong positive correlation between Ag concentration and dissolved silicic acid concentration. However, Ag is depleted relative to silicic acid at intermediate depths where dissolved O2 concentrations are low, implying a possible removal of Ag from oxygen-depleted waters by scavenging and/or precipitation.  相似文献   
52.
The electrification of wind-blown dust grains was studied in a series of laboratory experiments to examine how grain electrification depends on grain size, grain mineralogy, atmospheric composition, atmospheric pressure, and the method of dust dispersal. This work is intended to contribute to a deeper physical understanding of particle electrification on both Mars and Earth. Findings indicate that the amount of electrification per suspended particle generally is independent of dust entrainment process and atmospheric composition. As expected, the electrification process is grain size-dependent, with smaller grains predominantly electrifying negatively. Although there appears to be a weak dependence upon dust mineralogy, this work supports the expectation that dust suspended in the Martian atmosphere will be significantly electrified.  相似文献   
53.
In Latnjavagge, a 9-km2 drainage basin with homogeneous lithology in periglacial northern Swedish Lapland, water balance, water chemistry and radio magnetotelluric geophysical investigations along selected profiles were integrated with assessment of regolith thickness as well as of ground frost conditions within the basin. In combination with direct field observations, the geophysical profiles demonstrated presence of relatively thin regolith in most of the investigated area, yet in some parts, the bedrock was located deeper and locally was not detected at 40-m depth. TDS values of the water were generally very low. The areas that contributed with the lowest ion concentrations were cold and had a thin regolith, whereas there were higher concentrations in water that drained radiation exposed slopes with earlier thaw and thicker regolith. The low resistivities found along the profiles in the geophysical investigations in combination with the relatively higher TDS values found in related runoff and subsurface water samples showed that larger volumes of ice-rich frozen ground were not found along the investigated profiles in late August.  相似文献   
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55.
The commonly used, but no longer available, reference materials NIST SRM 976 (Cu) and ‘JMC Lyon’ (Zn) were calibrated against the new reference materials ERM®‐AE633, ERM®‐AE647 (Cu) and IRMM‐3702 (Zn), certified for isotope amount ratios. This cross‐calibration of new with old reference materials provides a continuous and reliable comparability of already published with future Cu and Zn isotope data. The Cu isotope amount ratio of NIST SRM 976 yielded δ65/63Cu values of ?0.01 ± 0.05‰ and ?0.21 ± 0.05‰ relative to ERM®‐AE633 and ERM®‐AE647, respectively, and a δ66/64ZnIRMM‐3702 value of ?0.29 ± 0.05‰ was determined for ‘JMC Lyon’. Furthermore, we separated Cu and Zn from five geological reference materials (BCR‐2, BHVO‐2, BIR‐1, AGV‐1 and G‐2) using a two‐step ion‐exchange chromatographic procedure. Possible isotope fractionation of Cu during chromatographic purification and introduction of resin‐ and/or matrix‐induced interferences were assessed by enriched 65Cu isotope addition. Instrumental mass bias correction for the isotope ratio determinations by MC‐ICP‐MS was performed using calibrator‐sample bracketing with internal Ni doping for Cu and a double spike approach for Zn. Our results for the five geological reference materials were in very good agreement with literature data, confirming the accuracy and applicability of our analytical protocol.  相似文献   
56.
International Journal of Earth Sciences - During the early Cambrian, the Danish island Bornholm was situated on the northern edge of the continent Baltica with palaeolatitudes of about 35°S....  相似文献   
57.
Subsidence within the main caldera of Askja volcano in the North of Iceland has been in progress since 1983. Here, we present new ground- and satellite-based deformation data, which we interpret together with new and existing micro-gravity data, to help understand which processes may be responsible for the unrest. From 2003 to 2007, we observe a net micro-gravity decrease combined with subsidence and from 2007 to 2009 we observe a net micro-gravity increase while the subsidence continues. We infer subsidence is caused by a combination of a cooling and contracting magma chamber at a divergent plate boundary. Mass movements at active volcanoes can be caused by several processes, including water table/lake level movements, hydrothermal activity and magma movements. We suggest that, here, magma movement and/or a steam cap in the geothermal system of Askja at depth are responsible for the observed micro-gravity variations. In this respect, we rule out the possibility of a shallow intrusion as an explanation for the observed micro-gravity increase but suggest magma may have flowed into the residing shallow magma chamber at Askja despite continued subsidence. In particular, variable compressibility of magma residing in the magma chamber as well as compressibility of the surrounding rock may be the reason why this additional magma did not create any detectable surface deformation.  相似文献   
58.
We have combined tensor radio magnetotelluric- (RMT, 15–250 kHz) and controlled source tensor magnetotelluric (CSTMT, 1–12 kHz) data for the mapping of aquifers in gravel formations lying in between crystalline bedrock and clay rich sediments in the Heby area some 40 km west of Uppsala in Sweden. The estimated transfer functions, the impedance tensor and the tipper vector generally satisfy 1D or 2D necessary conditions except for the lowest CSTMT frequencies where near field effects become more dominant.The data measured from 8 profiles were inverted with the Rebocc code of Siripunvaraporn and Egbert (2000) assuming plane wave conditions. This meant that only 12 frequencies in the range of 4–180 kHz could be used. The four lowest frequencies of CSTMT in the range of 1–2.8 kHz were excluded because of source effects. Data from all profiles were inverted with a starting model of 100 Ω-m and a relative error floor of 0.02 on apparent resistivity, corresponding to less than 1° on phase. Tipper vectors are generally small except when source effects become dominant in the lowest frequencies of CSTMT and were therefore not used for inversion. Comparing with models derived from vertical electrical soundings, refraction and reflection seismic data as well as ground truth from exploration wells assessed the reliability of the deep part of the models. Furthermore we carried out a non-linear resolution analysis to better quantify the depth extent of the aquifers.The inverted models from the Heby area show well the thickness variations of glacial deposits overlying crystalline bedrock. Generally, the upper 20 m of the models have resistivities below 40 Ω-m, taken to represent clay rich formations. Below the clay layer resistivities increase to about 40–400 Ω-m, interpreted to represent sand/gravel formations with a maximum thickness of about 40 m and a width of several hundred metres. This is a potential aquifer that extends in approximately N–S direction for some kilometres.  相似文献   
59.
Elastic behaviour of North Sea chalk: A well-log study   总被引:1,自引:1,他引:0  
We present two different elastic models for, respectively, cemented and uncemented North Sea chalk well‐log data. We find that low Biot coefficients correlate with anomalously low cementation factors from resistivity measurements at low porosity and we interpret this as an indication of cementation. In contrast, higher Biot coefficients and correspondingly higher cementation factors characterize uncemented chalk for the same (low) porosity. Accordingly, the Poisson's ratio–porosity relationship for cemented chalk is different from that of uncemented chalk. We have tested the application of the self‐consistent approximation, which here represents the unrelaxed scenario where the pore spaces of the rock are assumed to be isolated, and the Gassmann theory, which assumes that pore spaces are connected, as tools for predicting the effect of hydrocarbons from the elastic properties of brine‐saturated North Sea reservoir chalk. In the acoustic impedance–Poisson's ratio plane, we forecast variations in porosity and hydrocarbon saturation from their influence on the elastic behaviour of the chalk. The Gassmann model and the self‐consistent approximation give roughly similar predictions of the effect of fluid on acoustic impedance and Poisson's ratio, but we find that the high‐frequency self‐consistent approach gives a somewhat smaller predicted fluid‐saturation effect on Poisson's ratio than the low‐frequency Gassmann model. The Gassmann prediction for the near and potentially invaded zone corresponds more closely to logging data than the Gassmann prediction for the far, virgin zone. We thus conclude that the Gassmann approach predicts hydrocarbons accurately in chalk in the sonic‐frequency domain, but the fluid effects as recorded by the acoustic tool are significantly affected by invasion of mud filtrate. The amplitude‐versus‐angle (AVA) response for the general North Sea sequence of shale overlying chalk is predicted as a function of porosity and pore‐fill. The AVA response of both cemented and uncemented chalk generally shows a declining reflectivity coefficient versus offset and a decreasing normal‐incidence reflectivity with increasing porosity. However, for the uncemented model, a phase reversal will appear at a relatively lower porosity compared to the cemented model.  相似文献   
60.
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